| |
| |
| |
Remote Sensing Methods in the Atmosphere | |
| |
| |
| |
Lidar: An Overview | |
| |
| |
| |
Introduction | |
| |
| |
| |
Backscatter Lidar (Rayleigh-Mie-Lidar) | |
| |
| |
| |
DIAL | |
| |
| |
| |
Raman Lidar | |
| |
| |
| |
Doppler-Lidar | |
| |
| |
| |
Outlook | |
| |
| |
References | |
| |
| |
| |
Application Perspectives of Intense Laser Pulses in Atmospheric Diagnostics | |
| |
| |
| |
Introduction | |
| |
| |
| |
Interaction of Intense Laser Pulses With Air - Detection of Gases | |
| |
| |
| |
Interaction of Intense Laser Pulses with Microdroplets - Characterization of Aerosols | |
| |
| |
| |
Outlook | |
| |
| |
References | |
| |
| |
| |
Analysis of Three Dimensional Aerosol Distributions by Means of Digital Holography | |
| |
| |
| |
Abstact | |
| |
| |
| |
Introduction | |
| |
| |
| |
Digital Holography | |
| |
| |
| |
Storage of the Digital Hologram | |
| |
| |
| |
Digital Reconstruction of the Stored Volume | |
| |
| |
| |
Development of an Aerosol Analysis Aystem on the Basis of Digital Holography | |
| |
| |
| |
Analysis of Digitally Reconstructed Droplets | |
| |
| |
| |
Recognition of Droplets, Determination of Localization and Size | |
| |
| |
| |
Results | |
| |
| |
| |
Field Campaign FELDEX 2000 | |
| |
| |
| |
Discussion | |
| |
| |
Acknowledgement | |
| |
| |
References | |
| |
| |
| |
Applications in Liquid and Solid States | |
| |
| |
| |
Laser-Based Analysis of Solids with Environmental Impact | |
| |
| |
| |
Introduction | |
| |
| |
| |
Laser-Induced Fluorescence Spectroscopy | |
| |
| |
| |
Polycyclic Aromatic Hydrocarbons and Mineral Oils in Soils | |
| |
| |
| |
DDT on Wood | |
| |
| |
| |
Pesticides on Leaves | |
| |
| |
| |
Rock Identification | |
| |
| |
| |
Conclusion | |
| |
| |
| |
Laser-Induced Breakdown Spectroscopy | |
| |
| |
| |
Recycled Thermoplastics from Consumer Electronics Waste | |
| |
| |
| |
Inorganic Wood Preservatives | |
| |
| |
| |
Transformation of Spatial in Pseudo-Temporal Resolution | |
| |
| |
| |
Multi-Element Detection of Pollutants in Soil | |
| |
| |
| |
Combination Technique: LIBS-LIF | |
| |
| |
| |
Conclusion | |
| |
| |
| |
Vibrational Spectroscopy | |
| |
| |
| |
Infrared Spectroscopy | |
| |
| |
| |
Raman Spectroscopy | |
| |
| |
| |
Laser Ablation, Laser Desorption, Laser Ionization | |
| |
| |
| |
Mass Spectrometry | |
| |
| |
| |
Laser Ablation Inductively Coupled Plasma Mass Spectrometry | |
| |
| |
| |
Laser Ablation Inductively Coupled Plasma Optical Emission Spectrometry | |
| |
| |
| |
Resonance Enhanced Multi-Photon Ionization Time-of-Flight Mass Spectrometry | |
| |
| |
| |
Laser-based Ion Mobility Spectrometry | |
| |
| |
| |
Organic Wood Preservatives | |
| |
| |
| |
Polycyclic Aromatic Hydrocarbons in Soils | |
| |
| |
| |
Photo- and Optoacoustic Spectroscopy | |
| |
| |
| |
PCP Detection on Wood | |
| |
| |
| |
Determination of the Optical Properties of Human Skin | |
| |
| |
| |
Other Techniques and Outlook | |
| |
| |
References | |
| |
| |
| |
Laser-Induced Fluorescence (LIF) Spectroscopy for the In Situ Analysis of Petroleum Product-Contaminated Soils | |
| |
| |
| |
Introduction | |
| |
| |
| |
Experimental Techniques | |
| |
| |
| |
The LIF demonstrator unit | |
| |
| |
| |
The mobile LIF spectrometer OPTIMOS | |
| |
| |
| |
Investigated petroleum products and soil samples | |
| |
| |
| |
Results and Discussion | |
| |
| |
| |
Photophysical properties of the petroleum products | |
| |
| |
| |
LIF spectroscopic investigations of oil-spiked samples | |
| |
| |
| |
LIF spectroscopic investigations of real-world soils | |
| |
| |
| |
Field investigations | |
| |
| |
| |
Conclusions | |
| |
| |
Acknowledgment | |
| |
| |
References | |
| |
| |
| |
Laser Induced Breakdown Spectroscopy (LIBS) in Environmental and Process Analysis | |
| |
| |
| |
Introduction | |
| |
| |
| |
Plasma Generation | |
| |
| |
| |
Spectrochemical Analysis with Laser Plasmas | |
| |
| |
| |
Instrumentation | |
| |
| |
| |
Applications in Environmental and Process Analysis | |
| |
| |
| |
Solid Samples | |
| |
| |
| |
Liquid Samples and Colloids | |
| |
| |
| |
Gaseous Samples and Aerosols | |
| |
| |
| |
Conclusion and Outlook | |
| |
| |
References | |
| |
| |
| |
Intracavity-, Laser-Desorption- and Cavity Ring-Down Techniques as Detection Devices for Samples in Condensed Phases | |
| |
| |
| |
An Intracavity Laser Raman Detection Device for HPLC Chromatography | |
| |
| |
| |
Experimental Approach | |
| |
| |
| |
Results | |
| |
| |
| |
Laser Desorption Spectroscopy | |
| |
| |
| |
Cavity Ring-Down Spectroscopy of the Condensed Phase | |
| |
| |
| |
Introduction | |
| |
| |
| |
Current Status of the Development of Condensed Phase CRDS | |
| |
| |
| |
Further Developments of Mirror Coated Thin Film CRDS | |
| |
| |
| |
Improved Sensitivity of Detection by Utilizing the Dependence of Absorption on the Spatial Position of the Ultrathin Layer in the Electromagnetic Wave | |
| |
| |
| |
Extension of Our Method to Liquids | |
| |
| |
Acknowledgements | |
| |
| |
References | |
| |
| |
| |
Application of Two-Dimensional LIF for the Analysis of Aromatic Molecules in Water | |
| |
| |
| |
Introduction | |
| |
| |
| |
Hardware | |
| |
| |
| |
Overview | |
| |
| |
| |
Laser | |
| |
| |
| |
Detection System I | |
| |
| |
| |
Detection System II | |
| |
| |
| |
Current development | |
| |
| |
| |
Optimised Sensor Geometry | |
| |
| |
| |
Data processing and Calibration | |
| |
| |
| |
Introduction | |
| |
| |
| |
PLS-Calibration | |
| |
| |
| |
Applications | |
| |
| |
Acknowledgements | |
| |
| |
References | |
| |
| |
| |
Applications for Gaseous Substances and Aerosols | |
| |
| |
| |
Chemical Analysis with Multi-Dimensional and On-Line Selectivity Using Laser Spectroscopy Combined with Mass or Species Separation | |
| |
| |
| |
Introduction | |
| |
| |
| |
Resonant Laser Mass Spectrometry | |
| |
| |
| |
Laser-assisted Selective Detection in Chromatography | |
| |
| |
| |
Two-Dimensional Selectivity by Absorption/Emission Spectroscopy | |
| |
| |
| |
Laser-Assisted Analysis of Solid Samples | |
| |
| |
| |
Diode Lasers: A Step Toward Miniaturization of Laser-Based Chemical Analysis? | |
| |
| |
References | |
| |
| |
| |
Rapid Analysis of Complex Mixtures by Means of Resonant Laser Ionization Mass Spectrometry | |
| |
| |
| |
Introduction | |
| |
| |
| |
Principles of Laser Ionization Mass Spectrometry | |
| |
| |
| |
Resonant Multiphoton Ionization | |
| |
| |
| |
Time-of-flight mass spectrometry | |
| |
| |
| |
Laser desorption | |
| |
| |
| |
Application Examples | |
| |
| |
| |
On-line exhaust gas analysis | |
| |
| |
| |
Soil Analysis | |
| |
| |
| |
Conclusion | |
| |
| |
Acknowledgement | |
| |
| |
References | |
| |
| |
| |
Diode-Laser Sensors for In-Situ Gas Analysis | |
| |
| |
| |
Absorption Spectroscopy | |
| |
| |
| |
Mid-Infrared Diode-Laser Spectrometers | |
| |
| |
| |
Near-Infrared Overtone Spectrometer | |
| |
| |
| |
Quantum Cascade Lasers | |
| |
| |
| |
Quantum Limited Spectroscopy | |
| |
| |
References | |
| |
| |
| |
Applications in Life Science | |
| |
| |
| |
Laser Analytics of Gas Samples in Life Science | |
| |
| |
| |
Introduction | |
| |
| |
| |
Sources of Biological Gas Samples | |
| |
| |
| |
Composition of exhaled breath | |
| |
| |
| |
Other biological sources of gaseous emissions | |
| |
| |
| |
Instrumentation for Laser Analytics of Breath and Other Biological Gas Samples | |
| |
| |
| |
Sample collection and preparation | |
| |
| |
| |
Laser spectroscopic techniques | |
| |
| |
| |
Application of Breath Tests | |
| |
| |
| |
Monitoring of endogenous volatile diseasemarkers in breath | |
| |
| |
| |
Use of stable isotope markers for medical and pharmaceutical research | |
| |
| |
| |
Conclusion and Perspectives | |
| |
| |
References | |
| |
| |
| |
Detection of Nitric Oxide in Human Exhalation Using Laser Magnetic Resonance | |
| |
| |
| |
Free Radical Spectroscopy, a Challenge for Sensitive Detection | |
| |
| |
| |
Applied Spectroscopy using the LMR Method | |
| |
| |
| |
Dynamic Behaviour of NO in Exhalation | |
| |
| |
| |
Blood Pressure Regulating NO | |
| |
| |
| |
In-Vitro Investigations using LMR | |
| |
| |
| |
Applications in Pharmacology | |
| |
| |
| |
Future Development, Smaller and Simpler | |
| |
| |
Acknowledgements | |
| |
| |
References | |
| |
| |
| |
Medical Trace Gas Detection by Means of Mid-Infrared Cavity Leak-Out Spectroscopy | |
| |
| |
| |
Introduction | |
| |
| |
| |
The CO-Overtone Spectrometer | |
| |
| |
| |
Demonstration of Medical Applications with the CO-Overtone Spectrometer | |
| |
| |
| |
Oxidative Stress | |
| |
| |
| |
Measurements on Smokers | |
| |
| |
| |
Further Applications | |
| |
| |
| |
Transportable Setup (DFG Laser) | |
| |
| |
| |
Outlook | |
| |
| |
Acknowledgement | |
| |
| |
References | |
| |
| |
| |
Practical Applications of CRDS in Medical Diagnostics | |
| |
| |
| |
Introduction | |
| |
| |
| |
Cavity Ring-down Spectroscopy | |
| |
| |
| |
Applications | |
| |
| |
| |
Helicobacter Pylori Detection | |
| |
| |
| |
Analysis of the Exhaled Breath in Smokers | |
| |
| |
| |
Summary | |
| |
| |
References | |
| |
| |
| |
Photoacoustic Trace Gas Detection in Plant Biology | |
| |
| |
| |
Introduction | |
| |
| |
| |
The CO Overtone Laser Photoacoustic Spectrometer | |
| |
| |
| |
Characterization of the spectrometer | |
| |
| |
| |
Comparison of acetaldehyde detection with PAS and HPLC | |
| |
| |
| |
New Radiation Sources for PA Detection | |
| |
| |
| |
Photoacoustic detection with an optical parametric oscillator | |
| |
| |
| |
Application to Plant Physiology | |
| |
| |
| |
Ethylene and ethane from freezing damage | |
| |
| |
| |
Ethane and pentane from germinating peas | |
| |
| |
| |
Acetaldehyde emission from flooded poplar trees | |
| |
| |
| |
Summary | |
| |
| |
Acknowledgement | |
| |
| |
References | |
| |
| |
| |
DNA Adducts as Biomarkers for Carcinogenesis Analysed by Capillary Electrophoresis and Laser-Induced-Fluorescence Detection | |
| |
| |
| |
Significance of DNA Adducts | |
| |
| |
| |
Methods for Analyzing DNA Adducts | |
| |
| |
| |
Reproducibility, Fluorescence-Quenching Phenomenon and Labeling Efficiency | |
| |
| |
| |
Sensitivity | |
| |
| |
References | |
| |
| |
Index | |